LC-MS/MS-Based Assay for Free and Deconjugated Testosterone and Epitestosterone in Rat Urine and Serum

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LC-MS/MS-Based Assay for Free and Deconjugated Testosterone and Epitestosterone in Rat Urine and Serum

The 2014 World Anti-Doping Agency (WADA) Prohibited List shows testosterone and epitestosterone listed as class S1.1a and S1.1b, with its use banned in and out of competition [1]. Doping with testosterone is suspected if the urinary ratio of testosterone over epitestosterone (T/E) exceeds 4 [2]. According to the 2012 (WADA) laboratory statistics, elevated testosterone based on the testosterone ...

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The stability of testosterone glucuronide (TG), epitestosterone glucuronide (EG) and the T/E ratio in urine has been studied. Samples were analyzed by gas chromatography coupled to mass spectrometry (GC/MS). Urine samples were submitted to a solid-liquid cleanup followed by extraction of unconjugated testosterone (T) and epitestosterone (E) with tert-butyl methyl ether (free fraction). The rema...

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Development and method validation for testosterone and epitestosterone in human urine samples by liquid chromatography applications.

An isocratic high-performance liquid chromatographic method for the determination of testosterone (T) and epitestosterone (ET) in human urine using liquid-liquid or solid-phase extraction (SPE) is developed and validated. The optimum separation is achieved using a Hypersil C(18) column, water-acetonitrile (57:43, v/v) as the mobile phase and UV-absorbance detection at 245 nm. The recoveries obt...

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ژورنال

عنوان ژورنال: Journal of Analytical & Bioanalytical Techniques

سال: 2014

ISSN: 2155-9872

DOI: 10.4172/2155-9872.s5-006